January 1, 2014Open Access

A reusable CuII based metal–organic framework as a catalyst for the oxidation of olefins

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Resumen

The metal–organic framework Cu2(bipy)2(btec)∞ was used as a heterogeneous catalyst in the liquid phase oxidation of styrene and cyclohexene with tert-butylhydroperoxide (TBHP) as the oxidant either in water–dichloroethane or n-decane medium.

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Cancino et al. (Wed,) studied this question.

synapsesocial.com/papers/6a1ebc4de5c5a32e9d9a8510 https://doi.org/https://doi.org/10.1039/c4cy00152d

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1Ullmann's Encyclopedia of Industrial Chemistry2000 · 3,567 citations
2Epoxidation of olefins on M-SiO2 (M=Ti, Fe, V) catalysts with highly isolated transition metal ions prepared by ion beam implantation2000 · 23 citations
3The oxamate route, a versatile post-functionalization for metal incorporation in MIL-101(Cr): Catalytic applications of Cu, Pd, and Au2013 · 92 citations
4Hydrothermal synthesis of dimeric lanthanide compounds: X-ray structure, magnetic study and heterogeneous catalytic epoxidation of olefins2010 · 45 citations
5Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage1992 · 2,083 citations

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