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October 6, 2021JACS Au16 citationsOpen Access

Spectroscopic Evidence for a Cobalt-Bound Peroxyhemiacetal Intermediate

YSYeongjin SonKyungpook National University KKKyungmin KimKorea Atomic Energy Research Institute SKS.C. KimDaegu Gyeongbuk Institute of Science and Technology

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, whereas the reaction with acyl chlorides proceeds by a nucleophilic attack. The observation of the peroxyhemiacetal intermediate provides significant insight into the initial step of aldehyde deformylation by metalloenzymes.

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Spectroscopic Evidence for a Cobalt-Bound Peroxyhemiacetal Intermediate | Synapse

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Son et al. (Wed,) studied this question.

synapsesocial.com/papers/6a202497c1b320180d0e0190 https://doi.org/https://doi.org/10.1021/jacsau.1c00166

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