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We present the results of observations taken with the X-shooter spectrograph devoted to the study of quasars at z 6. This paper focuses on the properties of metals at high redshift traced, in particular, by the C IV doublet absorption systems. Six objects were observed with resolutions 27 and 34 km s -1 in the visual, and 37.5 and 53.5 km s -1 in the near-infrared. We detected 102 C IV lines in the range: 4.35 < z < 6.2 of which 27 are above z 5. Thanks to the characteristics of resolution and spectral coverage of X-shooter, we could also detect 25 Si IV doublets associated with the C IV at z 5. The column density distribution function of the C IV line sample is observed to evolve in redshift for z 5.3, with respect to the normalization defined by low-redshift (1.5 < z < 4) C IV lines. This behaviour is reflected in the redshift evolution of the C IV cosmic mass density, C IV , of lines with column density in the range 13.4 < log N(C IV) < 15, which is consistent with a drop of a factor of 2 for z 5.3. Considering only the stronger C IV lines (13.8 < log N(C IV) < 15), C IV gently rises by a factor of 10 between z 6.2 and z 1.5 with a possible flattening towards z 0. The increase is well fitted by a power law: C IV = (2 1) 10 -8 (1 + z)/4 -3.10.1 . An insight into the properties of the C IV absorbers and their evolution with redshift is obtained by comparing the observed column densities of associated C IV, Si IV and C II absorptions with the output of a set of CLOUDY photoionization models. As already claimed by cosmological simulations, we find that C IV is a good tracer of the metallicity in the low-density intergalactic medium (IGM) gas at z 5-6 while at z 3 it arises in gas with overdensity 100.
D’Odorico et al. (Mon,) studied this question.
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