Microstructure and high-temperature mechanical performance of industrial-scale titanium and chromium beryllides for fusion applications

The development of materials for the breeding blanket of future fusion devices requires a combination of high-temperature strength, radiation resistance, and compatibility with other materials. While beryllides have long been considered as neutron multipliers due to their favorable nuclear properties, their potential structural role has remained largely overlooked. These materials form an exotic class of beryllium-based intermetallics that may offer advantages in both neutronics and mechanical performance. We report the first comprehensive microstructural and mechanical characterization of full-scale TiBe 12 and CrBe 12 blocks fabricated by industrial vacuum hot pressing. TiBe 12 shows a fine-grained (≈7 µm) structure with ≈7% free beryllium and frequent twin boundaries, while CrBe 12 has coarser grains (≈40 µm) and 1000 HV) and strong room-temperature compressive strength (2030 MPa for TiBe 12 ; 1750 MPa for CrBe 12 ). Nanoindentation confirmed hardness values of 13.6–14.5 GPa and elastic moduli of 285 GPa (TiBe 12 ) and 304 GPa (CrBe 12 ). They retain strength at 1000°C (740 MPa and 460 MPa, respectively) and develop ductility above 850°C, with up to 20% deformation at 1200°C. In three-point bending, TiBe 12 reaches 540 MPa at 800°C, outperforming CrBe 12 and many other materials. The results are compared with available data on NbBe 12 and Ta 2 Be 17 , as well as with conventional high-temperature materials. Given that only very limited mechanical information exists for beryllides, this study substantially expands the database for this exotic class of compounds. In particular, the identification of twinning in TiBe 12 and the detailed comparison of strength, hardness, and elastic moduli provide new insights into their deformation behavior. Overall, the findings highlight the potential of TiBe 12 and CrBe 12 to bridge functional and structural roles, supporting their application not only in fusion blankets but also in aerospace, fission, and other extreme environments. • Industrial-scale TiBe 12 and CrBe 12 blocks were fabricated via vacuum hot pressing. • Both beryllides show high microhardness above 1000 HV and dense microstructures. • TiBe 12 and CrBe 12 retain compressive strength up to 740 MPa and 460 MPa at 1000°C. • Ductility appears above 850 °C, reaching 20% deformation at 1200°C without cracking. • The unique combination of strength and ductility makes beryllides promising for extreme environments.