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Gold(I)-Catalyzed Enantioselective 4 + 2-Cycloaddition of Allene-dienes | Synapse

December 4, 2009

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Gold(I)-Catalyzed Enantioselective 4 + 2-Cycloaddition of Allene-dienes

AGAna Z. GonzálezCalifornia Institute of Technology

F. Dean TosteOntario Institute for Cancer Research

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Resumen

An enantioselective gold(I)-catalyzed intramolecular 4 + 2-cycloaddition of allenes and dienes is reported. The reactions allow for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C(3)-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I) complexes as catalysts, respectively.

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Cite This Study

González et al. (Fri,) studied this question.

synapsesocial.com/papers/6a244cbca2806805a2a02864 https://doi.org/https://doi.org/10.1021/ol902622b

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