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May 30, 2026Materials Advances0 citationsOpen Access

CF 3 -Pyridyl-Substituted Hetero-and Homocyclic Conjugated Molecules: From Non-Emissive to Highly Emissive through Core Engineering

HYHasan YaqoobNANimra ArifRSRahman Shah Zaib Saleem

Key Points

  • The study aims to synthesize CF 3 -pyridyl-substituted conjugated molecules and evaluate their emission properties.
  • Synthesized six CF 3 -pyridyl-substituted aromatics through Suzuki-Miyaura cross-coupling.
  • Incorporated diverse heterocyclic and homocyclic cores for systematic investigation.
  • Analyzed emission variance based on structural modifications.
  • Achieved transition from non-emissive to highly emissive compounds by core engineering.
  • Measured emission intensity showed significant enhancement correlating with core electronic properties.
  • Identified relationships between molecular structure and fluorescence behavior.

Abstract

Herein, we report the synthesis of six CF 3 -pyridyl-substituted aromatics via Suzuki-Miyaura cross-coupling, incorporating electronically diverse heterocyclic (pyrazine, benzothiadiazole) and homocyclic (chrysene, anthracene, pyrene, perylene) cores to systematically probe...

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Cite This Study

Yaqoob et al. (2026) studied this question.

synapsesocial.com/papers/6a1a82640307b785094340a9https://doi.org/10.1039/d6ma00215c
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