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January 10, 2011Angewandte Chemie International Edition601 citations

Repeatable Photoinduced Self‐Healing of Covalently Cross‐Linked Polymers through Reshuffling of Trithiocarbonate Units

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YAYoshifumi AmamotoJKJun KamadaHOHideyuki Otsuka

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Abstract

Well-healed: Polymers cross-linked with trithiocarbonate (TTC) units were prepared by a RAFT polymerization. The repeatable self-healing systems or macroscopic fusions were accomplished by UV irradiation of the cross-linked polymer in solution and in the bulk state. The macroscopic fusion of completely separated parts was successful (see pictures, BA=n-butyl acrylate).

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Amamoto et al. (2011) studied this question.

synapsesocial.com/papers/6a1e6f261d1700dc27952e22https://doi.org/10.1002/anie.201003888
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