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February 23, 2017Advanced Materials247 citationsOpen Access

High Temperature‐Stable Perovskite Solar Cell Based on Low‐Cost Carbon Nanotube Hole Contact

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KAKerttu AitolaKDKonrad DomanskiJCJuan‐Pablo Correa‐Baena

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Abstract

Mixed ion perovskite solar cells (PSC) are manufactured with a metal‐free hole contact based on press‐transferred single‐walled carbon nanotube (SWCNT) film infiltrated with 2,2,7,‐7‐tetrakis(N,N‐di‐p‐methoxyphenylamine)‐9,90‐spirobifluorene (Spiro‐OMeTAD). By means of maximum power point tracking, their stabilities are compared with those of standard PSCs employing spin‐coated Spiro‐OMeTAD and a thermally evaporated Au back contact, under full 1 sun illumination, at 60 °C, and in a N 2 atmosphere. During the 140 h experiment, the solar cells with the Au electrode experience a dramatic, irreversible efficiency loss, rendering them effectively nonoperational, whereas the SWCNT‐contacted devices show only a small linear efficiency loss with an extrapolated lifetime of 580 h.

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Aitola et al. (2017) studied this question.

synapsesocial.com/papers/6a213d1f1b4b1c41cfc3bd67https://doi.org/10.1002/adma.201606398
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