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Salt metathesis between an alkali-stabilized tantalate complex and 3d transition metal halide dimers yields a series of nearly isostructural, rare perhydrocarbyl-stabilized heterobimetallic complexes that exhibit unusual coordination geometries and atypical α-hydrogen tautomerism. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

Probing Structural Diversity in a Series of Perhydrocarbyl Heterobimetallic Complexes Associating Tantalum and 3d (Cr, Mn, Fe, Co, Ni) Transition Metals

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