During their stay at the surface of the Earth, meteorites undergo terrestrial weathering. In particular, the iron-nickel alloys and iron sulfides that are abundant in many types of meteorites transform into oxides and oxihydroxides (magnetite, maghemite, akaganeite, etc.). Mössbauer spectroscopy is a powerful tool to identify these weathering products. However, distinguishing signals from different phases summed up in the Fe3+ paramagnetic doublets in the central part of the spectrum remains challenging. This study focuses on a detailed investigation of meteorite weathering products to separate signals from different secondary minerals formed on Earth in a series of weathered meteorites. We carried out a room-temperature Mössbauer spectroscopy study on seventy ordinary chondrites collected in the Atacama Desert, Chile, in order to make a comparative qualitative analysis of the mineralogy of their terrestrial weathering products. Based on these results, three samples showing a variety of weathering products (Catalina 146, Catalina 535, and El Médano 070) were selected for a detailed study and two of them for low-temperature Mössbauer study. We found that, above 200 K, most meteorites exhibit superparamagnetic magnetization dynamics attributable to strong dispersed maghemite–magnetite phase formed as a weathering product. On the other hand, other iron-bearing weathering products (goethite, akaganeite, hematite) demonstrate line shapes of the corresponding partial components that are close to the shapes of the bulk samples. Only two of the 70 measured meteorites showed no superparamagnetic behavior at room temperature.
Pyataev et al. (Thu,) studied this question.