Spent fluid catalytic cracking catalysts (E-cat) are a challenging waste from the petroleum refining industry, enriched with heavy metals such as nickel, vanadium, and iron. This study proposes a circular valorization strategy by incorporating E-cat into a chemically bonded iron phosphate ceramic matrix, known for its excellent waste stabilization properties. Composites were synthesized at room temperature using E-cat, hematite, and phosphoric acid, with E-cat contents from 0% to 35%. Characterization by XRF, XRD, SEM, compressive strength, and water absorption tests identified an optimal formulation containing 16% E-cat, achieving a maximum compressive strength of 16.6 MPa, 35% higher than the control. This improvement can be attributed to the dual function of E-cat, acting both as a micro-aggregate that promotes matrix densification and as a pozzolanic component that enhances mechanical reinforcement. These results demonstrate that iron phosphate ceramics represent a low-energy and sustainable strategy for the immobilization of spent catalysts and the production of durable construction composites.
Fraga et al. (Sun,) studied this question.