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Cooperative Metathesis of H-H/Sn-CAr bonds in stannylene-Ni0 systems | Synapse

February 26, 2026Open Access

Cooperative Metathesis of H-H/Sn-CAr bonds in stannylene-Ni0 systems

Key Points

To investigate the reaction of phosphine-appended stannylenes with nickel synthons to form metal complexes.
Synthesis of phosphine-appended (amido)(aryl)stannylenes
Reaction with Ni0 synthons
Characterization of chelating-stannylene Ni0 complexes
Utilization of carbene-stabilized synthons
Formation of stable chelating-stannylene Ni0 complexes
Demonstrated efficiency in the metathesis reaction
Potentiality for further applications in metal-organic chemistry

Abstract

The reaction of phosphine-appended (amido)(aryl)stannylenes (1) with Ni0 synthons leads to the facile formation of chelating-stannylene Ni0 complexes (2-4). Utilising the carbene-stabilised synthon IPr·Ni·(η6-toluene) (IPr = (H)CN(Dipp)2C:; Dipp = 2,6-iPr2C6H3)...

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Cite This Study

Gilch et al. (Thu,) studied this question.

synapsesocial.com/papers/699fe3ec95ddcd3a253e7fa0 https://doi.org/https://doi.org/10.1039/d5sc09496h