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March 14, 2026Open Access

Leveraging the Redox Activities of Cerium and Dibenzotetrathiafulvalene to Discover a Photo-Responsive Magnetic Material

Key Points

The research aims to explore the redox activities of cerium and dibenzotetrathiafulvalene in creating magnetic materials.
Synthesis of [DBTTF]4[Ce2Cl10] through light-induced crystallization.
Utilization of photo-oxidation of DBTTF to facilitate material formation.
Successful synthesis of a photo-responsive magnetic material.
Demonstrated effects of photo-oxidation on material properties.

Abstract

Stimuli-responsive changes in lanthanide-based materials are a promising research direction. In this study, DBTTF4Ce2Cl10 DBTTF = dibenzotetrathiafulvalene (1) was synthesized by a light-induced crystallization, where photo-oxidation of DBTTF enables formation...

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