This study investigates the effect of microstructure on water-induced embrittlement of dual-phase austempered ductile iron (ADI). Dual-phase ADI materials were produced by austenitization at 780, 800, 820, and 840 °C followed by austempering at 400 °C/1 h, resulting in microstructures composed of varying fractions of free ferrite and ausferrite. Tensile properties were evaluated under dry conditions and in distilled water. The embrittlement zones were observed in all samples investigated; however, they were not critical in all cases. The results indicate that free ferrite is less sensitive to water-induced embrittlement, whereas increasing ausferrite content promotes the formation and growth of the embrittlement zone. Elongation was identified as the most sensitive mechanical parameter, showing statistically significant reductions of up to ~80% for microstructures containing more than ~65% ausferrite, while proof strength remained largely unaffected. Fracture surface analysis revealed fatigue-like striation features within the embrittlement zone, indicating cyclic crack initiation and propagation. Based on correlations between tensile behavior, fracture morphology, and microstructural features, a water-induced embrittlement mechanism involving cyclic local chemisorption and surface-initiated crack growth is proposed. These findings highlight the critical roles of phase type, volume fraction, and spatial distribution in controlling the resistance of dual-phase ADI to embrittlement in aqueous environments.
Janjatović et al. (Wed,) studied this question.