September 13, 2005

Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47

Key Points

Key points are not available for this paper at this time.

Abstract

A distinct step in the isotherm occurs during the adsorption of CO2 on MIL-53 at 304 K. Such behavior is neither observed during the adsorption of CH4 on MIL-53 nor during the adsorption on the isostructural MIL-47. This phenomenon seems to be due to a different mechanism than that of previous adsorption steps on MOF samples. It is suggested that a breathing behavior is induced in MIL-53 during CO2 adsorption.

Bookmark

Cite This Study

Bourrelly et al. (Tue,) studied this question.

synapsesocial.com/papers/69dbae8d50e1971baba3c33b https://doi.org/https://doi.org/10.1021/ja054668v

Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Gravimetric measurement of binary gas adsorption equilibria of methane—carbon dioxide mixtures on activated carbon1995 · 62 citations
2Reticular synthesis and the design of new materials2003 · 9,002 citations
3Adsorbent storage of natural gas1996 · 155 citations
4High-Pressure Adsorption Equilibria of Methane and Carbon Dioxide on Several Activated Carbons2005 · 590 citations
5A Breathing Hybrid Organic–Inorganic Solid with Very Large Pores and High Magnetic Characteristics2002 · 968 citations

Bookmark