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January 1, 1978Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics612 citations

Dynamics of concentrated polymer systems. Part 3.—The constitutive equation

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MDMasao DoiSES. F. Edwards

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Abstract

The rheological constitutive equation of a condensed polymer system is presented based on the primitive chain model presented in Parts 1 and 2. The constitutive equation has the form of a BKZ equation and gives an explicit form for the memory kernel with the dependence of the rheological parameters on molecular weight and concentration. An interesting point is that it predicts a stress superposition law in the regime of non-linear viscoelasticity. The general features agree with experiments fairly well.

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Cite This Study

Doi et al. (1978) studied this question.

synapsesocial.com/papers/69dc908d7873f5f05b1335afhttps://doi.org/10.1039/f29787401818
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