A Review of Synthesis Methods, Modifications, and Mechanisms of ZnO/TiO2-Based Photocatalysts for Photodegradation of Contaminants

The environment being surrounded by accumulated durable waste organic compounds has become a critical crisis for human societies. Generally, organic effluents of industrial plants released into the water source and air are removed by some physical and chemical processes. Utilizing photocatalysts as cost-effective, accessible, thermally/mechanically stable, nontoxic, reusable, and powerful UV-absorber compounds creates a new gateway toward the removal of dissolved, suspended, and gaseous pollutants even in trace amounts. TiO2 and ZnO are two prevalent photocatalysts in the field of removing contaminants from wastewater and air. Structural modification of the photocatalysts with metals, nonmetals, metal ions, and other semiconductors reduces the band gap energy and agglomeration and increases the affinity toward organic compounds in the composite structures to expand their usability on an industrial scale. This increases the extent of light absorbance and improves the photocatalytic efficiency. Selecting a suitable synthesis method is necessary to prepare a target photocatalyst with distinct properties such as high specific surface area, numerous surface functional groups, and an appropriate crystalline phase. In this Review, significant parameters for the synthesis and modification of TiO2- and ZnO-based photocatalysts are discussed in detail. Several proposed mechanistic routes according to photocatalytic composite structures are provided. Some electrochemical analyses using charge carrier trapping agents and delayed recombination help to plot mechanistic routes according to the direction of photoexcited species (electron-hole pairs) and design more effective photocatalytic processes in terms of cost-effective photocatalysts, saving time and increasing productivity.