What question did this study set out to answer?

The aim is to synthesize and characterize dimeric cadmium complexes based on iminoacenaphthene.

May 10, 2026Journal of Structural Chemistry1 citations

Binuclear Cadmium (II) Complexes Based on 1, 2-bis- (2, 4, 6-trimethylphenyl) Iminoacenaphthene: Synthesis, Structure, and Electrochemical Properties

ЕЧЕ.В. ЧеховNovosibirsk State University IBI.V. BakaevNikolaev Institute of Inorganic Chemistry VKV.I. KomlyaginaNikolaev Institute of Inorganic Chemistry

Key Points

The aim is to synthesize and characterize dimeric cadmium complexes based on iminoacenaphthene.
Synthesized compounds are characterized using elemental analysis, 1H NMR, and IR spectrometry.
Molecular structures were determined by single crystal X-ray diffraction.
Electrochemical properties were examined using cyclic voltammetry.
Two distinct cadmium complexes [{Cd(tmp-bian)Br}2(μ-Br)2] and [{Cd(tmp-bian)I}2(μ-I)2] were successfully synthesized.
Electrochemical studies revealed unique behavior under cyclic voltammetry, indicating potential for material applications.

Abstract

Dimeric cadmium complexes based on 1, 2-bis- (2, 4, 6-trimethylphenyl) iminoacenaphthene (tmp-bian) are obtained. Their compositions are Cd (tmp-bian) Br2 (μ-Br) 2 (1) and Cd (tmp-bian) I2 (μ-I) 2 (2). The compounds synthesized are characterized by the elemental analysis, 1H NMR and IR spectrometry. Molecular structures of 1 and 2 are determined by single crystal X-ray diffraction. The electrochemical properties of the compounds are studied by cyclic voltammetry.

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