exhibits efficient photocatalytic activity for the oxy-thiocyanation of terminal alkenes using molecular oxygen as a green oxidant, producing valuable α-thiocyanato ketones in high yields (up to 87%) under mild conditions. The catalyst shows excellent stability and reusability over six cycles. This work not only broadens the family of actinide-incorporated polyoxometalates but also provides insights into their potential applications in organic synthesis.
Jiang et al. (Wed,) studied this question.