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, and 20 bar of oxygen. Accuracy was evaluated using the certified reference material NIST 1634c and by comparing the results as outlined by American Society for Testing and Materials (ASTM) methods D6470-99(2020) for Cl and D7876-13(2018) for S. The MIC demonstrated an agreement of >95% in both evaluations. To assess the environmental impact of the proposed and official methods, the White Analytical Chemistry metric was employed. This approach enabled us to evaluate the ecological, analytical, and practical parameters, yielding scores of 82.5 and 64.0 for Cl, and 81.9 and 64.4 for S, for MIC and the ASTM methods, respectively. Under optimized conditions, MIC combined with IC proved efficient for the simultaneous determination of Cl and S in crude oil, surpassing traditional ASTM methods in analytical accuracy, environmental impact, and operational practicality. The proposed method offers an alternative for routine analysis in petrochemical laboratories, providing faster processing, reduced reagent consumption, and diminished environmental impact.
Picoloto et al. (Wed,) studied this question.