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Five new, discretely sized, magic-size II-VI nanoclusters are synthesized in primary-amine bilayer templates and are isolated as the derivatives (CdS)(34)(n-butylamine)(18), (ZnS)(34)(n-butylamine)(34), (ZnSe)(13)(n-butylamine)(13), (CdTe)(13)(n-propylamine)(13), and (ZnTe)(13)(n-butylamine)(13). The nanoclusters are characterized by elemental analysis, UV-visible absorption spectroscopy, laser-desorption-ionization mass spectrometry, and transmission electron microscopy. Four of the nanocluster precursors are converted to wurtzitic CdS, ZnS, and ZnSe quantum platelets and CdTe quantum belts, respectively, under mild conditions.
Wang et al. (Tue,) studied this question.
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