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Silanolsynthese: Das lakunare Polyoxowolframat (nBu4N+)4γ-SiW10O34(H2O)2 (I) mit zwei Leerstellen ist ein effizienter Homogenkatalysator für die hoch selektive Oxidation von Organosilanen zu Silanolen mit 30–60 % H2O2. Silane 1 mit Aryl-, Alkyl-, Alkenyl-, Alkinyl- und Alkoxygruppen werden in hohen Ausbeuten chemoselektiv zu den jeweiligen Silanolen 2 umgesetzt, wobei nur ein Äquivalent an wässrigem H2O2 in Bezug auf das Substrat benötigt wird. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Ishimoto et al. (Wed,) studied this question.