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April 21, 2005The Journal of Chemical Physics47 citations

Modeling a tethered polymer in Poiseuille flow

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MWM. A. WebsterJYJulia M. Yeomans

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Abstract

We investigate the behavior of a tethered polymer in Poiseuille flow using a multiscale algorithm. The polymer, treated using molecular dynamics, is coupled to a solvent modeled by the stochastic rotation algorithm, a particle-based Navier-Stokes integrator. The expected series of morphological transitions of the polymer: sphere to distorted sphere to trumpet to stem and flower to rod are recovered, and we discuss how the polymer extension depends on the flow velocity. Backflow effects cause an effective increase in viscosity, which appears to be primarily due to the fluctuations of the free end of the polymer.

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Cite This Study

Webster et al. (2005) studied this question.

synapsesocial.com/papers/6a85696ff8226fba7f109824https://doi.org/10.1063/1.1884105
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