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January 15, 1999Angewandte Chemie International Edition71 citations

Formation of a Curved Silver Nitrate Network That Conforms to the Shape of C60 and Encapsulates the Fullerene—Structural Characterization of C60Ag (NO3) 5

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MOMarilyn M. OlmsteadKMKalyani MaitraABAlan L. Balch

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Abstract

Cocrystallization of a fullerene and an ionic component has been observed for the first time. Dark red, nearly black crystals of C60Ag (NO3) 5 (a section of the crystal structure is shown) form when solutions of C60 in benzene and Ag (NO3) in ethanol are mixed. The silver nitrate portion forms a zeolite-like network, in which rounded cavities are formed that are occupied by the fullerene molecules. Despite the good solubility of silver nitrate, C60Ag (NO3) 5 is stable when immersed in water for several hours.

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Olmstead et al. (1999) studied this question.

synapsesocial.com/papers/6a8bb8da8c2084202833a89dhttps://doi.org/10.1002/(sici)1521-3773(19990115)38:1/2<231::aid-anie231>3.0.co;2-5
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