Leveraging anion selection to modulate crystallographic symmetry in Yb(III) single-molecule magnets

Key Points

• Enhancing quantum tunnelling of magnetisation leads to improved slow magnetic relaxation.
• Transverse crystal field parameters introduced by symmetry distortions impact relaxation rates effectively.
• Assessment of local symmetry distortions highlights their crucial role in determining magnetic properties.
• Modulating anion selection may open avenues for novel single-molecule magnets design and functionality.