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Abstract The Upper Miocene Bongaya Formation coal, carbonaceous shale, and shale sediments were collected to investigate their origin, types, and maturity. The main objectives of this study were to verify and update previous claim of possible hydrocarbon showings and to gain new insights about the petroleum potential using different geochemical analysis approach. The primary methodology used in this study is the pyrolysis technique and coupled with petrographic analysis. The bulk geochemistry results revealed that the Bongaya sediments serve as favorable source rock, with the total organic carbon (TOC) content ranging from 0.90 to 63.10 wt% by weight, indicating fair to excellent organic richness. The coal samples exhibited the highest TOC values, followed by carbonaceous shale samples, while shale and coal laminated with sandstone samples displayed fair TOC amounts. Most of the Bongaya sediments analyzed in this study exhibited hydrogen index (HI) values of less than 200 mg HC/g TOC, indicating Type III organic matter, which signifies a significant influence of terrestrial organic matter. However, three coals displayed comparatively higher pyrolysis HI values, corroborated by Pyrolysis gas-chromatography (Py-GC) results and maceral types, indicating a mixture of Type II/III kerogen. This suggests that the Bongaya Formation sediment has the potential to generate gas with minor oil. Maceral analysis also revealed that most of the coal samples contained a high content of resinite maceral, which explains the waxy composition of the oil. The organic matter in the analyzed Bongaya sediments was found to be immature for petroleum generation, as evidenced by low huminite reflectance data (lower than 0.50% VR) and Tmax values between 372 and 432 °C. Consequently, the kerogen in the studied onshore Bongaya sediments has yet to enter the hydrocarbon cracking (catagenesis) phase before expelling petroleum. Therefore, it is essential to consider the offshore equivalent Bongaya sediments, which may be laterally extended offshore and buried at deeper depths to attain optimal maturity for hydrocarbon generation.
Azam et al. (Mon,) studied this question.