Exploring the general chemistry of the core and ocean of Enceladus

Measurements made by the Cassini spacecraft instruments were able to reveal the composition of the geysers of the Saturn moon, Enceladus, among which salts (sodium chloride, sodium bicarbonate and / or sodium carbonate) and traces of silica could be the result of hydrothermal processes from the interaction of an inner liquid ocean with the core of Enceladus. The chemistry of the ocean should be closely connected to the chemistry of the core. Even though. the actual composition of the core is unknown, Enceladus has been characterised as a moon with a silicate core and different authors have estimated the properties of the ocean. A core with a silicate composition alone, does not necessarily justify most of the observed species of the plume. Given the many uncertainties, in the current work, we study the possible chemistry of the core and the ocean in the context of a four-layered Enceladus (dry core, hydrated core, ocean and crust) with three different compositional scenarios for the core: primordial (represented by an ordinary chondrite), composite (represented by a carbonaceous chondrite with an igneous inclusion) and non primordial (epresented by a given peridotite). The scenarios comprise a set of minerals that interact with a primordial ocean (either pure or enriched water) at a given temperature and pressure, producing a series of secondary minerals and compounds, some of them, coincident with the chemical species observed in the geysers. Specifically, we make a chemical speciation for each proposed compositional scenario with the software PhreeqC, however our analysis is limited to the study of interactions that reach a given equilibrium. In particular, output values like the potential of hydrogen of the ocean or the saturation indices of mineral products may give us hints about the chemistry of the ocean and the core. We find that, based on the species observed in the plume, the actual composition of the core (and the ocean as well) poses a somewhat wide range of possible compositional scenarios and each of our proposed scenarios and their products justify, to some extent, the observations of the plume.