ABSTRACT The electronic structures of 2D transition metal dichalcogenides (TMDs) can be modulated by alloying, enhancing their catalytic properties and broadening applications. In this study, binary alloy nanosheets−W 1‐ x Nb x S 2 and Mo 1‐ x Nb x S 2 −were synthesized via colloidal reactions, achieving homogeneous atomic mixing across the full composition range, which surpasses selenide alloy mixing. Nb incorporation into WS 2 or MoS 2 nanosheets produces a more metallic phase, and density functional theory calculations confirm both the high degree of atomic mixing and the metallic character of the alloys. For the hydrogen evolution reaction (HER) in acidic electrolytes, these alloys exhibit enhanced catalytic activity when the Nb composition x is between 0.2 and 0.5, outperforming x = 0 and 1. Gibbs free energy calculations for hydrogen adsorption show that the metal and S atoms in the alloys become catalytically active, directly correlating with the improved HER performance. These findings offer valuable insight into how atomic‐scale alloying modulates the catalytic activity of TMDs for next‐generation catalytic applications.
Ihsan et al. (Fri,) studied this question.