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Solvent-induced structural transformation in luminescence-enhanced polymorphic ionic HOFs | Synapse

February 26, 2026

Solvent-induced structural transformation in luminescence-enhanced polymorphic ionic HOFs

Key Points

The central aim is to explore how solvent affects the structural and luminescent properties of polymorphic ionic HOFs.
Synthesize two polymorphic ionic HOFs (iHOF-64 and iHOF-65) using different solvents.
Regulate internal polarity and conjugation degree by using DMA solvent for iHOF-65.
iHOF-65 shows a fluorescence enhancement of 100 times compared to iHOF-64.
Decreased conjugation degree and internal polarity were noted in iHOF-65 due to solvent effects.

Abstract

In this study, two polymorphic iHOFs (iHOF-64/65) were synthesized. Due to decreased conjugation degree and reduced internal polarity regulated by the DMA solvent, iHOF-65 exhibited a 100 times fluorescence enhancement compared to iHOF-64.

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Cite This Study

Yang et al. (Thu,) studied this question.

synapsesocial.com/papers/699fe3ec95ddcd3a253e80d2 https://doi.org/https://doi.org/10.1039/d6cc00927a