Performance Development of Graphene-Modified Electrically Conductive High-Performance Cementitious Composites Under Sub-Zero Temperature Curing: Attempt Towards Infrastructure Construction in Cold Regions

Cement-based construction in cold regions faces severe challenges due to the dramatic retardation of hydration and strength development under sub-zero temperatures. Joule curing as a novel curing method showed certain advantages in solving this problem, while the curing efficiency was low for Joule curing under severely cold temperatures. This study systematically investigates the performance of graphene nanoplatelet (GNP)-modified electrically conductive cementitious composites under sub-zero temperature curing conditions. Joule curing method was employed to ensure a high-quality curing at ambient temperatures of −20 °C, −40 °C, and −60 °C. The results demonstrate that GNP incorporation significantly enhances electro-thermal performance. For the electrical conductivity of the specimens, the specimens containing 0.5 wt% GNP showed a much stable electric resistance development under severely cold environment, illustrating the value of 1169 Ω after 1 day Joule curing at the environmental temperature of −60 °C, which was 36% lower than the Ref. group. As for the curing temperature, the specimen with 0.5 wt% GNP effectively maintained the internal temperature within 50–60 °C during the 24 h curing period, even under extreme conditions. Mechanical tests reveal that the GNP-modified specimens exhibit remarkable strength retention, with the 0.5% GNP composite maintaining 86.3% of its compressive strength and 95.9% of its flexural strength at −60 °C compared to standard curing values. Microstructural characterization through XRD and TG analyses confirms that while the crystalline phase composition remains unchanged across different curing regimes, the hydration degree directly correlates with the mechanical performance, explaining the observed strength variations. MIP analysis further proved the advantage of Joule curing on refining the microstructure for the specimens. The findings establish that GNP modification, combined with Joule curing, presents an effective strategy for winter concrete construction, ensuring adequate strength development through enhanced electrical conductivity and controlled internal curing temperature, without altering the fundamental hydration chemistry.