Ligand-effect regulated selective catalytic oxidation of 2-chloroethyl ethyl sulfide in aqueous phase by Keplerate-type molybdenum-oxygen cluster Mo 132 | Synapse
March 4, 2026RSC Advances0 citationsOpen Access
Ligand-effect regulated selective catalytic oxidation of 2-chloroethyl ethyl sulfide in aqueous phase by Keplerate-type molybdenum-oxygen cluster Mo 132
The aim is to assess the effectiveness of Keplerate-type molybdenum-oxygen clusters in selective catalytic oxidation.
Utilized aqueous phase for oxidation reactions.
Applied H2O2 as the oxidant.
Investigated ligand-based charge regulation effects on catalysis.
Achieved efficient selective oxidation of 2-chloroethyl ethyl sulfide.
Confirmed the role of ligand effects in regulating catalyst charge.
Showed that water as a solvent enhances catalyst performance.
Abstract
Keplerate-type nano-polyoxometalates are efficient catalysts for selective CEES oxidation using water as solvent and H 2 O 2 as oxidant, whilst revealing ligand-based catalyst charge regulation effect.