This research aims to explore the synthesis of reversibly interconvertible redox states of boradigermaallyl.
Synthesizing a methyl derivative of chloro-boradigermaallyl through reaction with MeBBr2.
Performing potassium graphite (KC8) reduction to generate derivatives.
Characterizing the resulting redox states.
Successful synthesis of both BCl and BMe derivatives of boradigermaallyl.
Demonstrated reversible interconversion between the radical allyl anion and allyl dianion forms.
Abstract
A methyl derivate of our previously published chloro-boradigermaallyl is synthesized by addition of MeBBr2 to the bis(germylene) A followed by KC8 reduction. Both derivatives, the BCl (1a) and BMe (1b)...
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Three reversibly interconvertible redox states of boradigermaallyl: syntheses of radical allyl anion and allyl dianion | Synapse