Atroposelective synthesis of N–N axially chiral pyrrolyl(aza)-quinolinone by de novo ring formation

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Abstract

A chiral phosphoric acid-catalyzed Paal–Knorr reaction was achieved for constructing axially chiral pyrrolyl(aza)quinolinones with ‘6–5’-membered rings as a new family member of N–N atropisomers.

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Huang et al. (Mon,) studied this question.

synapsesocial.com/papers/69d99fef9a6164e50fa3d19f https://doi.org/https://doi.org/10.1039/d3qo01877f

Discussion

Journals

Organic Chemistry Frontiers

Institutions

Shanghai University

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