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May 1, 1959The Journal of Chemical Physics509 citations

Free Energy of a Nonuniform System. II. Thermodynamic Basis

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JCJohn W. Cahn

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Abstract

The thermodynamic treatment of nonuniform systems of Cahn and Hilliard is shown to be equivalent to the self-consistent thermodynamic formalism of Hart. All parameters of the two treatments have been rigorously related and key equations have been shown to be equivalent.

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John W. Cahn (1959) studied this question.

synapsesocial.com/papers/6a11d9ac5a604c357c21a953https://doi.org/10.1063/1.1730145
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