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The atomic N-electron wave function of the independent-pair approximation is defined in terms of orbital configurations of one-electron functions and symmetry-adapted pair functions in the form of partial-wave (PW) expansions. This form is convenient for an extensive use of irreducible tensor operators. The formulation was used to set up a variational-perturbation scheme for closed-shell atoms in the case of the Rayleigh-Schr\"odinger perturbation theory with the symmetric sum of Hartree-Fock operators for the zerothorder Hamiltonian (RS-HFPT). A detailed study of the second- and third-order correlation energies of Ne is made in order to analyze the nature of various correlation effects. All PW's up to l^', l^''9 are considered. Particular attention is given to the problem of eliminating the radial basis saturation errors. The upper bound to the second-order energy is determined by means of 13 880 nonoptimized configurations to be -0. 38638 a. u. , which represents 99. 3% of the "experimental" correlation energy. Extrapolation of the pair energies for l^', l^''>9 results in a second-order energy of -0. 3879 a. u. (99. 7% of the total correlation energy). The PW expansions for the (ns, n^'s) pairs are compared for He, Be, and Ne. Remarkable regularities are observed, indicating that the PW formulation represents a convenient tool for the investigations of correlation effects. The third-order energy obtained for a shorter expansion of the first-order wave function amounts to 0. 00245 a. u. A discussion of the relative importance of the diagonal and off-diagonal contributions is presented, and detailed comparisons with the results of many other methods are made. It turned out that the RS-HFPT approach in the present formulation has several advantages over other perturbation methods.
Jankowski et al. (Tue,) studied this question.