We investigate the role of a statistical complexity measure to assign equilibration in isolated quantum systems. While unitary dynamics preserve global purity, expectation values of observables often exhibit equilibration-like behavior, raising the question of whether a measure of complexity can track this process. In addition to examining observable equilibration, we extend our analysis to study how the complexity of the quantum states evolves, providing insight into the transition from initial coherence to equilibrium. We define a classical statistical complexity measure based on observable entropy and deviation from equilibrium, which captures the dynamical progression towards equilibration and effectively distinguishes between complex and non-complex trajectories. In particular, our measure is sensitive to non-complex dynamics. Such dynamics include the quasi-periodic behavior exhibited by low-dimensional initial states, where the system explores a limited region of Hilbert space while preserving coherence. Numerical simulations of an Ising-like non-integrable Hamiltonian spin-chain model support these findings. Our work provides new insight into the emergence of equilibrium behavior from unitary dynamics and advances complexity as a meaningful tool in the study of the emergence of classicality in microscopic systems.
Alpino et al. (Sun,) studied this question.