The integration of electric vehicles (EVs) into smart grids (SGs) is reshaping both energy systems and mobility infrastructures. This review presents a comprehensive and cross-disciplinary synthesis of current technologies, methodologies, and challenges associated with EV–SG interaction. Unlike prior reviews that address these aspects in isolation, this work uniquely connects three critical pillars: (i) the evolution of energy storage technologies, including lithium-ion, second-life, and hybrid systems; (ii) optimisation and predictive control techniques using artificial intelligence (AI) for real-time energy management and vehicle-to-grid (V2G) coordination; and (iii) cybersecurity risks and post-quantum solutions required to safeguard increasingly decentralised and data-intensive grid environments. The novelty of this review lies in its integrated perspective, highlighting how emerging innovations, such as federated AI models, blockchain-secured V2G transactions, digital twin simulations, and quantum-safe cryptography, are converging to overcome existing limitations in scalability, resilience, and interoperability. Furthermore, we identify underexplored research gaps, such as standardisation of bidirectional communication protocols, regulatory inertia in V2G market participation, and the lack of unified privacy-preserving data architectures. By mapping current advancements and outlining a strategic research roadmap, this article provides a forward-looking foundation for the development of secure, flexible, and grid-responsive EV ecosystems. The findings support policymakers, engineers, and researchers in advancing the technical and regulatory landscape necessary to scale EV–SG integration within sustainable smart cities.
Cavus et al. (Fri,) studied this question.