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In high-level nuclear waste (HLW) repositories, concrete and compacted bentonite are designed to be employed as buffer materials, which may raise a problem of interactions between concrete and bentonite. These interactions would lead to mineralogy transformation and buffer performance decay of bentonite under the near field environment conditions in a repository. A small-scale experimental setup was established to simulate the concrete-bentonite-site water interaction system from a potential nuclear waste repository in China. Three types of mortars were prepared to correspond to the concrete at different degradation states. The results permit the determination of the following: (1) The macro-properties of Gaomiaozi (GMZ) bentonite (e.g. swelling pressure, permeability, the final dry density, and water content of reacted samples); (2) The composition evolution of fluids from the synthetic site water-concrete-bentonite interaction systems; (3) The sample characterization including Fourier transform infrared spectroscopy (FTIR) and X-ray powder diffraction (XRD). Under the infiltration of the synthesis Beishan site water (BSW), the swelling pressure of bentonite decreases slowly with time after reaching its second swelling peak. The flux decreases with time during the infiltrations, and it tends to be stable after more than 120 d. Due to the cation exchange reactions in the BSW-concrete-bentonite systems, the divalent cations (Ca and Mg) were consumed, and the monovalent cations (Na and K) were released. The dissolution of minerals in the bentonite such as albite causes Si increasing in the pore water. It was concluded that the hydro-mechanical property degradation of bentonite takes place when it comes into contact with concrete mortar, even under low-pH groundwater conditions. The soil dispersion, the uneven water content, and the uneven dry density in bentonite samples may partly contribute to the swelling decay of bentonite. Therefore, the direct contact with concrete has an obvious effect on the performance of bentonite.
Sun et al. (Sat,) studied this question.