We have measured the branching ratio BR (Φ → π⁰ π⁰ γ) with the KLOE detector using a sample of ~5x10⁷Φ decays. Φ mesons are produced at DAFNE, the Frascati Φ-factory. We find BR (Φ → π⁰ π⁰ γ) = (1. 09 ± 0. 03 (stat) ± 0. 05 (syst) ) x10^-4. We fit the two--pion mass spectrum to models to disentangle contributions from various sources.
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