Efficient Aggregation‐Induced Emission Manipulated by Polymer Host Materials

Linear copolymer hosts bearing a number of pillar5arene dangling side chains are synthesized for the facile construction of highly emissive supramolecular polymer networks (SPNs) upon noncovalently cross-linking with a series of tetraphenyethylene (TPE)-based tetratopic guests terminated with different functional groups through supramolecular host-guest interactions. An extremely high fluorescence quantum yield (98.22%) of the SPNs materials is obtained in tetrahydrofuran (THF) by fine-tuning the parameters, and meanwhile supramolecular light-harvesting systems based on spherical supramolecular nanoparticles are constructed by interweaving 9,10-distyrylanthracene (DSA) and TPE-based guest molecules of aggregation-induced emission (AIE) with the copolymer hosts in the mixed solvent of THF/H2 O. The present study not only illustrates the restriction of the intramolecular rotations (RIR)-ruled emission enhancement mechanism regulated particularly by macrocyclic arene-containing copolymer hosts, but also suggests a new self-assembly approach to construct high-performance light-harvesting materials.