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Another form of molecular self-assembly—the threading and unthreading of ring-shaped molecules on a polymer chain (represented schematically here) was studied by NMR spectroscopy and followed qualitatively for the formation of polymeric inclusion compounds made up of cyclodextrins and poly-(iminooligomethylene)s. The structures of the polymeric inclusion compounds are proven by their conversion to polyrotaxanes.
Wenz et al. (Sat,) studied this question.
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