Nonperturbative decay of an atomic system in a cavity

Atoms can nowadays be placed in increasingly exotic environments such as microscopic cavities and materials with photonic band gaps. High-Q cavities can now easily result in a strong coupling between an atom and its environment where perturbation theory should no longer be appropriate. The purpose of this paper is to describe the dynamics of a multilevel V-type atomic system (including the case of a two-level system) which interacts with a reservoir modeled by a generalized density of states. A theoretical construct, the pseudomode, is utilized to develop general methods for solution. Without using perturbation theory the equivalent master equation is developed and the relationship between the master equation, the pseudomodes, and the generalized density of states function is explored with examples. Utilizing a straightforward definition of the pseudomode, it is found that many functions for the density of states lead to problematic non-Lindblad master equations. Several examples are given, and it is shown how to convert the non-Lindblad master equations into a Lindblad form in these cases. The examples include a non-Lorentzian resonance and a simple model of a photonic band gap.