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Co(NH3)2NO22I3Cl 단결정에서의 비정상적인 결합 포토이성화 | Synapse

January 1, 2024

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Co(NH3)2NO22I3Cl 단결정에서의 비정상적인 연결 포토이성화

PKPolina P. KalininaNovosibirsk State University BZB.A. ZakharovNovosibirsk State University

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Abstract

Co(NH3)5NO2 2+ → Co(NH3)5ONO2+ 반응은 Co(NH3)5NO2 2 I3 Cl에서 특정 결정학적 위치에 있는 양이온에 대해 가시광선 하에서 진행되며, 이는 같은 결정 구조 내에서 반응성의 "결정학적 조절"을 시사합니다.

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Kalinina 외 연구자들(Mon,)이 이 질문을 연구했습니다.

synapsesocial.com/papers/69decba35e217d93a5558968 https://doi.org/https://doi.org/10.1039/d4ce00734d

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Also Consider

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1A comparison of the isostructural [Co(NH<sub>3</sub>)<sub>5</sub>NO<sub>2</sub>]<i>X</i>NO<sub>3</sub> and [Co(NH<sub>3</sub>)<sub>5</sub>ONO]<i>X</i>NO<sub>3</sub>, <i>X</i> = Cl<sup>−</sup> or Br<sup>−</sup> in relation to nitro–nitrito linkage isomerization and photomechanical effects2024 · 4 citations
2Distortion of Crystal Structures of Some Co<sup>III</sup> Ammine Complexes. I. Distortion of Crystal Structure of [Co(NH<sub>3</sub>)<sub>5</sub>NO<sub>2</sub>]Cl(NO<sub>3</sub>) on Cooling1997 · 36 citations
3Crystal space analysis by means of Voronoi–Dirichlet polyhedra1995 · 152 citations
4Reactivity of molecular solids1999 · 137 citations
5Distortion of Crystal Structures of Some Co<sup>III</sup> Ammine Complexes. III. Distortion of Crystal Structure of [Co(NH<sub>3</sub>)<sub>5</sub>NO<sub>2</sub>]Cl<sub>2</sub> at Hydrostatic Pressures up to 3.5 GPa1998 · 54 citations