One of the main challenges in hydrogen production via electrolysis is the reliable measurement of the electrical work supplied. In this work, a robust electronic data acquisition system was developed to obtain precise and accurate data to evaluate the electrical work. The electrolytic concentration and electrical work were the main variables in this study. The supplied electrical energy was analyzed under both constant and pulsed voltage conditions. The results reveal that hydrogen production depends on voltage amplitude, PWM, and electrolyte concentration. The applied voltage shows a slight positive correlation with hydrogen production. PWM influences hydrogen production in the range of 0 to 1 Hz, while no significant effect is observed at higher frequencies. Electrolyte concentration has a stronger influence on hydrogen production in the range of 0.125 to 0.25 M. The optimal operating conditions were identified at 0.375 M, 1 Hz and 6 VDC, and under these conditions the hydrogen production is 0.145 mL/s and the specific energy is 165 kWh/kg.
Jiménez-Becerra et al. (Sun,) studied this question.