Recent Advances on Host–Guest Material Systems toward Organic Room Temperature Phosphorescence

The design and characterization of purely organic room-temperature phosphorescent (RTP) materials for optoelectronic applications is currently the focus of research in the field of organic electronics. Particularly, with the merits of preparation controllability and modulation flexibility, host-guest material systems are encouraging candidates that can prepare high-performance RTP materials. By regulating the interaction between host and guest molecules, it can effectively control the quantum efficiency, luminescent lifetime, and color of host-guest RTP materials, and even produce RTP emission with stimuli-responsive features, holding tremendous potential in diverse applications such as encryption and anti-counterfeiting, organic light-emitting diodes, sensing, optical recording, etc. Here a roundup of rapid achievement in construction strategies, molecule systems, and diversity of applications of host-guest material systems is outlined. Intrinsic correlations between the molecular properties and a survey of recent significant advances in the development of host-guest RTP materials divided into three systems including rigid matrix, exciplex, and sensitization are presented. Providing an insightful understanding of host-guest RTP materials and offering a promising platform for high throughput screening of RTP systems with inherent advantages of simple material preparation, low-cost, versatile resource, and controllably modulated properties for a wide range of applications is intended.