A Unified Cobalt-Electrocatalytic Platform for Enantio- and Stereo-selective C−H and C−F Functionalization of gem-Difluoromethylene Allenes

Key Points

• The aim is to develop a cobalt-electrocatalytic platform for selective functionalization of C−H and C−F bonds.
• Utilized asymmetric electrocatalysis for simultaneous cleavage of C−H and C−F bonds.
• Explored the functionalization of gem-difluoromethylene allenes to create valuable chiral compounds.
• Demonstrated successful enantioselective reactions with significant yields.
• Achieved precise control over stereochemistry in C−H and C−F bond transformations.