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The ratios of the mean-square amplitudes of vibration at a surface to those in the bulk have been studied in detail for model crystals whose particles interact through a Lennard-Jones potential. Within a quasiharmonic approximation, the ratio for a particular surface and direction of vibration is approximately a universal function of T{₃}, where T is the temperature and ₃ the bulk Debye temperature. The ratio increases rapidly with T for T<12₃ and then is nearly constant. Three factors increase the ratio above the value it would have in a simple force-constant model: (i) a temperature-independent decrease in the force constants at the surface relative to those in the bulk, (ii) a further temperature-dependent decrease, and (iii) anharmonicity. These factors may account for the tendency of experimental values of this ratio to be larger than values calculated with force-constant models.
Allen et al. (Mon,) studied this question.