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Novel 1,3,5-tris(oligothienyl)benzenes have been synthesized by an efficient and very easy trimerization reaction and their optimized three-dimensional geometry has been determined by semiempirical computations. Their electrochemical behavior has been investigated; their electropolymerization with 2,2′-bithiophene led to the development of two- or three-dimensional conducting polymers.
Chérioux et al. (Wed,) studied this question.