September 23, 2005

Temperature- or Guest-Induced Drastic Single-Crystal-to-Single-Crystal Transformations of a Nanoporous Coordination Polymer

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Abstract

Aside from a temperature-induced structural transformation, a new nanoporous coordination polymer Ag6Cl(atz)4.OH.6H2O (Hatz = 3-amino-1,2,4,-triazole) comprised of interpenetrated Ag3(atz)2 coordination nets exhibits a single-crystal-to-single-crystal transformation of a 5-fold to 6-fold net interpenetration change triggered by guest desorption/absorption.

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Zhang et al. (Fri,) studied this question.

synapsesocial.com/papers/6a1d9169cc9f7df1b705a3b3 https://doi.org/https://doi.org/10.1021/ja054913a

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