A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts

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Abstract

Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl)benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.

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Shultz et al. (Mon,) studied this question.

synapsesocial.com/papers/6a2e08db5ad0045a7cd0e597 https://doi.org/https://doi.org/10.1021/ja900203f

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